Vertical migration of elements from mineral deposits   总被引：1，自引：0，他引：1  

Issai S. Goldberg 《Journal of Geochemical Exploration》1998,61(1-3)

There is currently widespread interest in the exploration community worldwide in the development of methods to locate deeply buried mineralisation. In the application of geochemical methods, some success has been achieved using the selective extraction of mobile and weakly bonded forms of elements (MWBE) in overburden. Studies in Russia commenced in the 1960s, and have continued in Russia and in other countries to the present time. This paper presents some examples of experimental and applied research carried out in Russia, specifically by members of VITR and then VIRG NPO Rudgeofizika (St. Petersburg). In particular, some characteristics of MWBE anomalies and rates of MWBE migration are illustrated, with reference to several case studies in geochemical exploration for base metal and precious metal deposits.  相似文献   

Marine geochemistry—2: scavenging redux     

Edward D. Goldberg  Minoru Koide  Kathe Bertine  Vern Hodge  Martha Stallard  Darko Martincic  Nevenka Mikac  Marco Branica  Jamal K. Abaychi 《Applied Geochemistry》1988,3(6)

Inorganic surfaces sorb dissolved and particulate phases from seawater onto organic films from a variety of sources. Heavy metals such as Au, Pt, Mn and Cd come to the coatings primarily from particulate phases. This observation confirms a previous finding of this laboratory for the uptake of U, Pu and Po. With depth in the open ocean there are greater contributions from the dissolved phases. Microbial and photochemical processes can enrich surfaces in some metals through reduction reactions. Copper and Mn enrichments in the films are attributed to the photo-reductions of Cu(II) to Cu(I) and manganese oxides to Mn(II), respectively, while the uptake of Mo is a consequence of the reduction, mediated by organisms, of molybdate to Mo(V) or Mo(IV). Cadmium, on the other hand, appears to be bioaccumulated in the films.  相似文献   

Flexibility and adaptation: some cues for social systems from nature     

Michael A. Goldberg 《Geoforum》1985,16(2):179-190

Complex socioecological systems exist amid great uncertainty. Indeed, much information concerning the environments within which such systems function is likely to remain unknowable. However, over an evolutionary timespan, successful systems develop strategies and tactics for coping with such uncertainty. The present paper describes some of these coping strategies and then extends them to the decision-making process for human-centred socioecological systems to derive an alternative approach to dealing with uncertainty which differs significantly from that encountered in traditional decision analysis.  相似文献   

Comparative environmental chemistries of metals and metalloids     

Edward D. Goldberg 《Marine pollution bulletin》1984,15(8):281-284

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Volatile (S,Cl and F) and fluid mobile trace element compositions in melt inclusions: implications for variable fluid sources across the Kamchatka arc   总被引：2，自引：0，他引：2  

Tatiana Churikova  Gerhard Wörner  Nikita Mironov  Andreas Kronz 《Contributions to Mineralogy and Petrology》2007,154(2):217-239

Volatile element, major and trace element compositions were measured in glass inclusions in olivine from samples across the Kamchatka arc. Glasses were analyzed in reheated melt inclusions by electron microprobe for major elements, S and Cl, trace elements and F were determined by SIMS. Volatile element–trace element ratios correlated with fluid-mobile elements (B, Li) suggesting successive changes and three distinct fluid compositions with increasing slab depth. The Eastern Volcanic arc Front (EVF) was dominated by fluid highly enriched in B, Cl and chalcophile elements and also LILE (U, Th, Ba, Pb), F, S and LREE (La, Ce). This arc-front fluid contributed less to magmas from the central volcanic zone and was not involved in back arc magmatism. The Central Kamchatka Depression (CKD) was dominated by a second fluid enriched in S and U, showing the highest S/K₂O and U/Th ratios. Additionally this fluid was unusually enriched in ⁸⁷Sr and ¹⁸O. In the back arc Sredinny Ridge (SR) a third fluid was observed, highly enriched in F, Li, and Be as well as LILE and LREE. We argue from the decoupling of B and Li that dehydration of different water-rich minerals at different depths explains the presence of different fluids across the Kamchatka arc. In the arc front, fluids were derived from amphibole and serpentine dehydration and probably were water-rich, low in silica and high in B, LILE, sulfur and chlorine. Large amounts of water produced high degrees of melting below the EVF and CKD. Fluids below the CKD were released at a depth between 100 and 200 km due to dehydration of lawsonite and phengite and probably were poorer in water and richer in silica. Fluids released at high pressure conditions below the back arc (SR) probably were much denser and dissolved significant amounts of silicate minerals, and potentially carried high amounts of LILE and HFSE. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

Contact metamorphic P–T–t paths from Sm–Nd garnet ages, phase equilibria modelling and thermobarometry: Garnet Ledge, south-eastern Alaska, USA     

H. H. Stowell  D. L. Taylor  D. L. Tinkham  S. A. Goldberg  K. A. Ouderkirk 《Journal of Metamorphic Geology》2001,19(6):645-660

Sm–Nd garnet‐whole rock geochronology, phase equilibria, and thermobarometry results from Garnet Ledge, south‐eastern Alaska, provide the first precisely constrained P–T–t path for garnet zone contact metamorphism. Garnet cores from two crystals and associated whole rocks yield a four point isochron age for initial garnet growth of 89.9 ± 3.6 Ma. Garnet rims and matrix minerals from the same samples yield a five point isochron age for final garnet growth of 89 ± 1 Ma. Six size fractions of zircon from the adjacent pluton yield a concordant U–Pb age of 91.6 ± 0.5 Ma. The garnet core and rim, and zircon ages are compatible with single‐stage garnet growth during and/or after pluton emplacement. All garnet core–whole rock and garnet rim‐matrix data from the two samples constrain garnet growth duration to ≤5.5 my. A garnet mid‐point and the associated matrix from one of the two garnet crystals yield an age of 90.0 ± 1.0 Ma. This mid‐point result is logically younger than the 90.7 ± 5.6 Ma core–whole rock age and older than the 88.4 ± 2.5 Ma rim‐matrix age for this sample. A MnNaCaKFMASH phase diagram (P–T pseudosection) and the garnet core composition are used to predict that cores of garnet crystals grew at 610 ± 20 °C and 5 ± 1 kbar. This exceeds the temperature of the garnet‐in reaction by c. 50 °C and is compatible with overstepping of the garnet growth reaction during contact metamorphism. Intersection of three reactions involving garnet‐biotite‐sillimanite‐plagioclase‐quartz calculated by THERMOCALC in average P–T mode, and exchange thermobarometry were used to estimate peak metamorphic conditions of 678 ± 58 °C at 6.1 ± 0.9 kbar and 685 ± 50 °C at 6.3 ± 1 kbar, respectively. Integration of pressure, temperature, and age estimates yields a pressure‐temperature‐time path compatible with near isobaric garnet growth over an interval of c. 70 °C and c. 2.3 my.  相似文献   

Solar abundance determination from ultraviolet emission lines     

Andrea K. Dupree  Leo Goldberg 《Solar physics》1967,1(2):229-241

The intensities of far ultraviolet emission lines from the solar corona are analyzed to determine relative coronal abundances for oxygen, silicon, and iron. Dielectronic recombination is included in the formulation of ionization equilibrium. Observations of solar radio emission are used to obtain abundances relative to hydrogen. The absolute coronal abundances appear to be in agreement with their respective photospheric values. General properties of the structure of the chromosphere and corona are deduced from the analysis of observed emission in the ultraviolet and radio wavelength regions.  相似文献   

Diffuse Component Spectra of Solar Active Regions at Submillimeter Wavelengths     

Adriana?V.?R.?SilvaEmail author  Tatiana?F.?Laganá  C.?Guillermo?Gimenez?De?Castro  Pierre?Kaufmann  Joaquim?E.?R.?Costa  Hugo?Levato  Marta?Rovira 《Solar physics》2005,227(2):265-281

Solar maps at 212 and 405 GHz obtained by the Solar Submillimetric Telescope (SST) show regions of enhanced brightness temperature, which coincide with the location of active regions. A statistical study of the radio emission from these active regions was performed for the first time at such high frequencies during 23 days on June and July 2002, when the atmospheric opacity was low. The brightest regions on the maps were chosen for this study, where the brightness excess observed varies from 3 to 20% above quiet Sun levels (i.e., 200–1000 K) at both wavelengths. Sizes of the regions of enhanced emission calculated at half the maximum value were estimated to be between 2′ and 7′. These sizes agree with observed sizes of active regions at other wavelengths such as Hα and ultraviolet. An important result is that the flux density spectra of all sources increase toward submillimeter frequencies, yielding flux density spectral index with an average value of 2.0. The flux density of the active region sources were complemented with that from maps at 17 and 34 GHz from the Nobeyama Radio Heliograph. The resulting spectra at all four frequencies were fit considering the flux density to be due to thermal bremsstrahlung from the active region. In the calculations, the source radius was assumed to be the mean of the measured values at 212 and 405 K. The effective temperatures of the radio emitting source, assumed homogeneous, obtained from this fit were 0.6–2.9 × 10⁴ K, for source diameters of 2′–7′.  相似文献   

Source ambiguity from an estimation of the scaling exponent of potential field power spectra     

Tatiana Quarta  Maurizio Fedi  & Angelo De Santis 《Geophysical Journal International》2000,140(2):311-323

An analysis of the field scaling power spectrum yields useful information about the source distribution, but it is uncertain whether deterministic, random, fractal or mixed approaches have to be used for the interpretation. To this end, the scaling properties of potential field spectra are analysed for a number of different source models of geological interest. Besides the models of Naidu (purely random sources) and Spector and Grant (gross block statistical ensembles) we consider other types of density and magnetization distributions with spectral exponents in the fractal range, such as a single homogeneous body with a random white source distribution. Spectral slopes in the fractal range are obtained.
We also study the effects of important natural sources, such as salt domes and sedimentary basins, representing them with simple Gaussians or combinations of Gaussian signals. The same spectral slopes as for gravity signals generated by 3-D fractal source distributions are found for them. Hence the power law decay of the field is not a characteristic only of fractal source models.
If a 3-D fractal source distribution is assumed a priori , a way of verifying the goodness of the model is to examine the whitened field at source level. The probability that the whitened field derives from a random white population is estimated for synthetic and real anomalies by applying the usual statistical tests.  相似文献   

Effects of local drought condition on public opinions about water supply and future climate change     

Jason?M.?EvansEmail author  Jon?Calabria  Tatiana?Borisova  Diane?E.?Boellstorf  Nicki?Sochacka  Michael?D.?Smolen  Robert?L.?Mahler  L.?Mark?Risse 《Climatic change》2015,133(2):193-208

A growing body of research indicates that opinions about long-term climate change and other natural resource issues can be significantly affected by current weather conditions (e.g., outside air temperature) and other highly contingent environmental cues. Although increased severity and frequency of droughts is regarded as a likely consequence of anthropogenic climate change, little previous research has attempted to relate the experience of drought with public attitudes about water supply or water-related climate change issues. For this study, a large set (n?=?3,163) of public survey data collected across nine states of the southern United States was spatio-temporally linked with records of short-term (~12 weeks) and long-term (~5 years) drought condition at the level of each respondent’s zip code. Multivariate ordinal logistic regression models that included numerous other independent variables (environmental ideology, age, gender, education, community size, residency duration, and local annual precipitation) indicated highly significant interactions with long-term drought condition, but showed no significant effect from short-term drought condition. Conversely, attitudes about water-related climate change showed highly significant interactions with short-term drought, with weaker to no effects from long-term drought. While the finding of significant effects from short-term drought condition on opinions about future drought is broadly consistent with previous public opinion research on climate change, the finding of water supply attitudes being more responsive to longer term drought condition is, to our knowledge, a novel result. This study more generally demonstrates the methodological feasibility and applied importance of accounting for local drought condition when public opinion information is used to evaluate outreach programs for water conservation and climate change.  相似文献